88791-44-0Relevant articles and documents
Kinetics of Anilinodechlorination of 3-Bromo- and 3-Methoxy-2-thenoyl Chlorides in Benzene
Consiglio, Giovanni,Spinelli, Domenico,Fisichella, Salvatore,Alberghina, Gaetano,Noto, Renato
, p. 1559 - 1562 (2007/10/02)
The susceptibility constants measured for the reaction of 3-bromo- (Ia) and 3-methoxy-2-thenoyl (Ic) chlorides with some meta- and para-substituted anilines in benzene at 25 deg C have confirmed the occurrence of two different mechanisms for the anilinodechlorination of 3-substituted 2-thenoyl chlorides: (i) the classical AE mechanism and (ii) the IP mechanism (unusual for reactions with anilines in nonpolar aprotic solvents) which can operate when electron-releasing substituents are present in the thiophen ring.