88799-12-6

Basic information

• Product Name: 4-Brom-N,N-dimethylanilin-Brom-Addukt
• Synonyms: 4-Brom-N,N-dimethylanilin-Brom-Addukt
• CAS NO: 88799-12-6
• Molecular Weight: 359.886
• Mol File: 88799-12-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Brom-N,N-dimethylanilin-Brom-Addukt(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Brom-N,N-dimethylanilin-Brom-Addukt(88799-12-6)
• EPA Substance Registry System: 4-Brom-N,N-dimethylanilin-Brom-Addukt(88799-12-6)

Safety Data

• Hazardous Substances Data: 88799-12-6(Hazardous Substances Data)

Upstream product

• 586-77-6 4-bromo-N,N-dimethylaniline 

Downstream Products

• 366-29-0 N,N,N',N'-tetramethylbenzidine 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 64230-27-9 2,4-dibromo-N,N-dimethylaniline 
• 73557-58-1 2,4-dibromo-N-methylaniline 
• 81090-57-5 2,4,6-tribromo-N-methylaniline 
• 81090-52-0 2,4-dibromo-N,N-diethylaniline 

Relevant articles and documents

Aminobenzenes, XVII. Addition Products of N,N-Dialkylanilines and Bromine - Synthesis and Reactions

4-Bromo-N,N-dialkylanilines 1 react with bromine in inert solvents to give the 1:1 addition compounds 2 or 3.IR and UV investigations established the structure of the isolated products to be CT complexes (? complexes) for 2 and N-bromoanilinium bromides for 3.The adducts 2 react to yield substitution products 6 and dealkylation products 7 in polar solvents (dimethylformamide, acetic acid, methanol), whereas the main product from 2a by reaction in acetone is N,N,N',N'-tetramethylbenzidine (9).Radical cations 10 are postulated to be the determining intermediates for these reactions.The tendency of the alkyl groups to be cleaved off decreases in the order isopropyl > ethyl > methyl.Under analogous conditions the N-bromo compounds 3 give predominantly the anilines 1 and only small amounts of substitution products 6, dealkylation and reaction to benzidines were not observed.