888188-20-3Relevant academic research and scientific papers
Sulfonylamidation of alkylbenzenes at benzylic position with p-toluenesulfonamide and 1,3-diiodo-5,5-dimethylhydantoin
Baba, Haruka,Togo, Hideo
experimental part, p. 2063 - 2066 (2010/06/19)
Treatment of alkylbenzenes with p-toluenesulfonamide and 1,3-diiodo-5,5-dimethylhydantoin (DIH) in a small amount of carbon tetrachloride at 60 °C gave the corresponding α-p-toluenesulfonylamido)alkylbenzenes in good to moderate yields. The present reaction is a simple method for the α-sulfonylamidation of the benzylic position in alkylbenzenes.
Iodine-catalyzed intermolecular hydroamination of vinyl arenes
Yadav,Reddy, B.V. Subba,Rao, T. Srinivasa,Krishna, B. Bala M.
experimental part, p. 5351 - 5353 (2009/12/06)
The vinyl arenes undergo smooth hydroamination with sulfonamides in the presence of 10 mol % of iodine to furnish tosyl and mesyl-protected secondary amines in excellent yields in short reaction times. The use of inexpensive and readily available molecula
