888321-08-2

Basic information

• Product Name: [PtCl(4-C₆H₅C₆H₃CHNCH₂CH₂NMe₂)]
• CAS NO: 888321-08-2
• Molecular Weight: 481.884
• Mol File: 888321-08-2.mol

Chemical Properties

• CAS DataBase Reference: [PtCl(4-C₆H₅C₆H₃CHNCH₂CH₂NMe₂)](CAS DataBase Reference)
• NIST Chemistry Reference: [PtCl(4-C₆H₅C₆H₃CHNCH₂CH₂NMe₂)](888321-08-2)
• EPA Substance Registry System: [PtCl(4-C₆H₅C₆H₃CHNCH₂CH₂NMe₂)](888321-08-2)

Safety Data

• Hazardous Substances Data: 888321-08-2(Hazardous Substances Data)

Downstream Products

• 888321-16-2 [PtCl₃(4-C₆H₅C₆H₃CHNCH₂CH₂NMe₂)] 

Relevant articles and documents

A comparative study of metallating agents in the synthesis of [C,N,N′]-cycloplatinated compounds derived from biphenylimines

The reactions of ligands 4-C6H5C6H 4CHNCH2CH2NMe2 (1a) and 2-C 6H5C6H4CHNCH2CH 2NMe2 (1b) in front of cis-[PtCl2(dmso) 2] or cis-[PtPh2(SMe2)2] produced compounds [PtCl2{4-C6H5C6H 4CHNCH2CH2NMe2}] (2aCl) and [PtCl2{2-C6H5C6H 4CHNCH2CH2NMe2}] (2bCl) or [PtPh2{4-C6H5C6H 4CHNCH2CH2NMe2}] (2aPh) and [PtPh2{2-C6H5C6H 4CHNCH2CH2NMe2}] (2bPh). From all these compounds, the corresponding cyclometallated [C,N,N′] platinum(II) compounds 3aCl, 3bCl, 3aPh and 3bPh were obtained although under milder conditions and with higher yields for the phenyl derivatives. The reaction of compounds 3aPh and 3bPh with methyl iodide gave cyclometallated [C,N,N′] platinum(IV) compounds 4aPh and 4bPh of formula [PtMePhI{C6H 5C6H3CHNCH2CH2NMe 2}]. Compounds 3aCl and 3bCl containing a chloro ligand, although unreactive towards methyl iodide, undergo oxidative addition of chlorine to produce the corresponding platinum(IV) compounds [PtCl3{4-C 6H5C6H3CHNCH2CH 2NMe2}] (6aCl and 6bCl). All compounds were characterised by NMR spectroscopy and crystal structures of compounds 3bCl and 6bCl are also reported.