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[Rh(CO)2((S)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl)]SbF6 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

888478-36-2

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888478-36-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 888478-36-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,8,8,4,7 and 8 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 888478-36:
(8*8)+(7*8)+(6*8)+(5*4)+(4*7)+(3*8)+(2*3)+(1*6)=252
252 % 10 = 2
So 888478-36-2 is a valid CAS Registry Number.

888478-36-2Downstream Products

888478-36-2Relevant academic research and scientific papers

Resolution of BIPHEP on Rh with a chiral diene auxiliary

Faller,Wilt, Jeremy C.

, p. 2207 - 2212 (2007/10/03)

Resolution of the atropisomeric chiral BIPHEP ligand on Rh has been achieved with the aid of 2-(4-tert-butyl-phenyl)-8-methoxy-1,8-dimethyl-bicyclo[2.2.2]octa-2,5-diene, a chiral chelating diene ligand. The diene complex 3 containing an (S)-BIPHEP ligand was found to be configurationally stable in CDCl3 solution at RT. Conversion of the diene complex 3 to a dicarbonyl Rh complex 4 that had a barrier of 25.0 kcal/mol for atropisomerization of the BIPHEP ligand. Preliminary studies of the use of the resolved complex 3 for catalysis are presented.

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