88854-22-2Relevant academic research and scientific papers
Synthesis of Ketones by Cyclization of Cyano and Acetylenic Radicals: Use of δ-Hydroxy Nitriles and δ- or ε-Hydroxy Acetylenes
Clive, Derrick L. J.,Beaulieu, Pierre L.,Set, Lu
, p. 1313 - 1314 (2007/10/02)
The radical intermediates generated by deoxygenation of alcohols undergo intramolecular ring closure when suitably located triple bonds (CC or CN) are present; the reaction provides a new synthesis of bicyclic ketones from either monocyclic ketones or cyclic olefins.
