888955-94-0

Basic information

• Product Name: 3β,17β-bis(tert-butyldimethylsilyloxy)-7α-benzyloxymethylandrost-5-en-7β-ol
• Synonyms: 3β,17β-bis(tert-butyldimethylsilyloxy)-7α-benzyloxymethylandrost-5-en-7β-ol
• CAS NO: 888955-94-0
• Molecular Weight: 655.122
• Mol File: 888955-94-0.mol

Chemical Properties

• CAS DataBase Reference: 3β,17β-bis(tert-butyldimethylsilyloxy)-7α-benzyloxymethylandrost-5-en-7β-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3β,17β-bis(tert-butyldimethylsilyloxy)-7α-benzyloxymethylandrost-5-en-7β-ol(888955-94-0)
• EPA Substance Registry System: 3β,17β-bis(tert-butyldimethylsilyloxy)-7α-benzyloxymethylandrost-5-en-7β-ol(888955-94-0)

Safety Data

• Hazardous Substances Data: 888955-94-0(Hazardous Substances Data)

Upstream product

• 3587-60-8 Benzyloxymethyl chloride 
• 357923-28-5 3β,17β-bis[(1,1-dimethylethyl)dimethylsilyl]oxyandrost-5-en-7-one 

Relevant articles and documents

Synthesis of 7-substituted-5-androstene derivatives promoted by SmI 2

The 7-substituted-5-androstene derivatives 2a-10a and 2b-10b were prepared by reaction of 3β,17β-di(tert-butyldimethylsilyloxy)-5-androsten-7-one 1 with different organic halides. The resulting 7α- and 7β-isomers were carefully separated by column chromat

Two novel approaches toward stereoselective introduction of β-hydroxymethyl group at the C-7 position of 5-androstene

Two novel approaches to stereoselective introduction of 7β-hydroxymethyl group onto 5-androstene have been developed. In the first approach, coupling of benzyloxymethyl chloride with the 7-carbonyl group of 1 mediated by SmI2 gives, after deben