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1-N-3',4',5,6-tetra-O-benzoyl-1,3,2'-tri-N-p-tolylsulfonylparomamine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

88897-26-1

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88897-26-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 88897-26-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,8,8,9 and 7 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 88897-26:
(7*8)+(6*8)+(5*8)+(4*9)+(3*7)+(2*2)+(1*6)=211
211 % 10 = 1
So 88897-26-1 is a valid CAS Registry Number.

88897-26-1Relevant articles and documents

SYNTHETIC ROUTES FROM PAROMAMINE TO THE OCTODIOSE-CONTAINING PSEUDODISACCHARIDE PRESENT IN (OXY)APRAMYCIN

Martin, Olivier R.,Szarek, Walter A.

, p. 195 - 220 (2007/10/02)

The synthesis of a 4-O-(2-amino-2-deoxyoctodiosyl)-2-deoxystreptamine, the first synthetic analog of the unusual pseudodisaccharide present in (oxy)apramycin was accomplished, starting from paromamine, by a two-carbon chain-elongation and a stereoselective cis-hydroxylation of the resulting E-unsaturated octuronate to give either ethyl 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-D-threo-α-D-gluco- (12) or -L-threo-α-D-gluco-octo-1,5-pyranosid> uronate.Mehtoxide-mediated deacylation of 12 afforded in one step a bicyclic, trans-decalone-like urono-8',4'-lactone (14) that was highly sensitive to acid-catalyzed alcoholysis and had properties in sharp contrast to those of D-glucurono-6,3-lactone.Partial reduction of lactone 14 or of the corresponding methyl octuronate 12 with lithium aluminum hydride at low temperature gave the expected α-D-threo-D-gluco-octodialdo-1,5-pyranoside-8,4-pyranose, which was methanolyzed and N-detosylated to afford the free pseudodisaccharide 1-(2-deoxystreptamin-4-yl) 8-methyl (8R,S)-2-amino-2-deoxy-α-D-threo-D-gluco-octodialdo-1,5:8,4-dipyranodioside.All of the octodiose derivatives were found to adopt a rigid, dipyranoid structure.

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