88929-50-4

Upstream product

• 62774-40-7 methyl 3-azido-4-O-benzoyl-6-bromo-2,3,6-trideoxy-β-D-ribo-hexopyranoside 
• 729597-56-2 N-tert-butoxycarbonyl-4-aminohept-6-ene-2,3-diol 
• 115204-89-2 (2S,3R,4S)-4-Amino-hept-6-ene-2,3-diol 
• 62812-43-5 N-((2R,3S,4S,6R)-3-Hydroxy-6-methoxy-2-methyl-tetrahydro-pyran-4-yl)-benzamide 
• 58769-78-1 N-((2R,3S,4S,6S)-3-Hydroxy-6-methoxy-2-methyl-tetrahydro-pyran-4-yl)-acetamide 
• 88885-28-3 (4S,5S)-5-((R)-1-Benzyloxy-ethyl)-4-(2,2-dimethoxy-ethyl)-oxazolidin-2-one 
• 88885-23-8 (4S,5S)-4-Allyl-5-((R)-1-benzyloxy-ethyl)-oxazolidin-2-one 
• 88885-24-9 (3aR,4S,6S,7aR)-6-Methoxy-4-methyl-hexahydro-pyrano[4,3-d]oxazol-2-one 
• 88885-24-9 (3aR,4S,6R,7aR)-6-Methoxy-4-methyl-hexahydro-pyrano[4,3-d]oxazol-2-one 

Relevant academic research and scientific papers

α-aminoallylation of aldehydes with ammonia: Stereoselective synthesis of homoallylic primary amines

Three-component reactions of aldehydes, ammonia, and allylboronates were found to provide homoallylic primary amines in high yields with high chemo- and stereoselectivities. A two-step, one-pot, stereoselective synthesis of an uncommon α-amino acid, alloisoleucine, was achieved utilizing this reaction. Copyright

A divergent route to 3-amino-2,3,6-trideoxysugars including branched sugar: Synthesis of vancosamine, daunosamine, saccharosamine, and ristosamine

Four 3-amino-2,3,6-trideoxysugars were synthesized by a divergent route from a single enone 9a. The Migita-Stille coupling introduced a methyl group at the 3-position. Stereoselective reduction of enone and the Mitsunobu reaction provided both β- and α-hy

ACYCLIC STEREOSELECTION. 19. TOTAL SYNTHESIS OF (+/-)-RISTOSAMINE AND (+/-)-MEGALOSAMINE.

(+/-)-Ristosamine (1) has been synthesized in seven straigthforward operations from ketone 5 and O-benzyllactaldehyde.The key step is a stereoselective aldol addition reaction in which diastereomeric aldols 7 and 8 are produced in a ratio of 78:22.A simpl