88958-73-0Relevant academic research and scientific papers
A CONVENIENT SYNTHESIS OF KETOXIMES FROM GRIGNARD REAGENTS AND NITRO COMPOUNDS ACTIVATED BY N,N-DIMETHYLCHLOROMETHYLENIMINIUM CHLORIDE
Fujisawa, Tamotsu,Kurita, Yoshitsugu,Sato, Toshio
, p. 1537 - 1540 (1983)
Ketoximes were synthesized in high yields with a new carbon-carbon bond formation by regioselective nucleophilic attack of Grignard reagents at the α-position of aci-nitroalkanes activated by N,N-dimethylchloromethyleniminium chloride in the presence of a catalitic amount of copper(I) iodide under mild conditions.
