88972-89-8Relevant academic research and scientific papers
FORMATION OF α-SILYLVINYLLITHIUM REAGENTS: REACTIONS OF α-SILYL- AND α-STANNYL-VINYLLITHIUMS WITH ALDEHYDES AND KETONES
Mitchell, Terence N.,Reimann, Werner
, p. 163 - 172 (2007/10/02)
The formation of α-trimethylsilylvinyllithium compounds from 1-trimethylsilyl-1-trimethylstannyl-1-alkenes have been studied and their stabilities investigated. α-Trimethylsilyl- and α-trimethylstannyl-vinyllithiums undergo 1,2-addition to aldehydes and non-enolisable ketones, to give silyl- or stannyl-substituted allylic alcohols; α,β-unsaturated ketones, however, undergo 1,4-addition to give homoallylic ketones.
1-BROMO-1-(TRIMETHYLSILYL)-1-ALKENES. A SINGLE SYNTHON FOR BOTH THE CARBONYL ANION AND CATION
Miller, R. B.,Al-Hassan, M. I.,McGarvey, G.
, p. 969 - 976 (2007/10/02)
The utility of 1-bromo-1-(trimethylsilyl)-1-alkenes as a single synthon for both the carbonyl anion and cation is demonstrated.
