88980-78-3

Basic information

• Product Name: 1-p-tolyl-2-phenyl-1-propanol
• CAS NO: 88980-78-3
• Molecular Weight: 226.318
• Mol File: 88980-78-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-p-tolyl-2-phenyl-1-propanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-p-tolyl-2-phenyl-1-propanol(88980-78-3)
• EPA Substance Registry System: 1-p-tolyl-2-phenyl-1-propanol(88980-78-3)

Safety Data

• Hazardous Substances Data: 88980-78-3(Hazardous Substances Data)

Upstream product

• 34713-70-7 2-Phenylpropanal 
• 4294-57-9 para-methylphenylmagnesium bromide 

Downstream Products

• 14161-82-1 rac-1-(4-methylphenyl)-2-phenylpropan-1-one 
• 22985-85-9 erythro-2-(4-Methyl-phenyl)-3-phenyl-butanol-⁽²⁾ 
• 22985-85-9 threo-2-(4-Methyl-phenyl)-3-phenyl-butanol-⁽²⁾ 

Relevant articles and documents

MECANISME DE L'ADDITION NUCLEOPHILE AU GROUPEMENT CARBONYLE-I. INFLUENCE DE LA NATURE DU SUBSTITUANT POLAIRE SUR LA STEREOCHIMIE ET LA REACTIVITE DANS LES REACTIONS D'ADDITION DE BROMURE DE METHYLMAGNESIUM AUX ARYL-1 PHENYL-2 PROPANONES

The influence of a m- or p-polar substituent in 1-aryl 2-phenyl propanones, on addition reactions with CH3MgBr in ether at 30 deg C has been investigated.The invariability of asymmetric induction as a function of substituent, and the correlation of rate constant ratios with Hammett ? constants (ρ=0.24, r=0.97), are consistent with a four-centre pericyclic concerted mechanism with concomitant departure of a solvent molecule.