89024-10-2Relevant academic research and scientific papers
Performic Acid Oxidation of Dihydro-o-hydroxyaroylacetylbenzopyrans: A New Synthesis of Dihydropyranoflavonols and Their Dehydro Analogues
Iyer, P. R.,Iyer, C. S. Rukmani,Prasad, K. J. Rajendra
, p. 1052 - 1054 (2007/10/02)
Performic acid oxidation of dihydro-o-hydroxyaroylacetylbenzopyrans (Ia-c and Va-c) in chloroform gives the dihydropyranoflavonols (IIa-c and VIa-c respectively).Methylation of IIa-b and VIa-b with dimethyl sulphate and aqueous sodium carbonate affords the corresponding dihydropyranomethoxyflavones (IIIa-b and VIIa-b) and benzylic bromination of IIIa-b and VIIa-b with N-bromosuccinimide followed by dehydrobromination with pyridine, affords the pyranomethoxyflavones (IVa-b and VIIIa-b respectively).
