89041-50-9Relevant academic research and scientific papers
Regio- and Stereo-selective Reaction of 1,3-Disubstituted Allyl Anions with Aldehydes via η3-Allyltitanium Compounds
Sato, Fumie,Uchiyama, Hiroshi,Iida, Katsumi,Kobayashi, Yuichi,Sato, Masao
, p. 921 - 922 (1983)
The regio- and stereo-chemistry in reactions of 1,3-disubstituted allyl anions with aldehydes can be controlled via η3-allyltitanium compounds and this provides a simple method for the preparation of threo-4-hydroxy-3-methyl-cis-1-phenoxyhex-1-ene (3b) and threo-4-hydroxy-3-trimethylsilyl-trans-1-trimethylsilylhex-1-ene (3d).
