890659-59-3Relevant academic research and scientific papers
Substitution reactions of mono-, di- and tri-thiocarbonato complexes of iron
El-khateeb, Mohammad,Mansor, Alaa,Jibril, Ibrahim,Rüffer, Tobias,Lang, Heinrich
, p. 63 - 67 (2017)
The photolytic reactions of iron thiocarbonato complexes CpFe(CO)2SC(Y)Y′R [Y?=?Y′?=?O; R?=?2-C6H4Cl (1), 4-C6H4Cl (2); Y?=?S, Y′?=?O; R?=?C6H4F (3), Y?=?Y′?=?S; R?=?Ph (4)] with EPh3 (E?=?P, As, Sb) are performed. Monosubstituted complexes of the general formula CpFe(CO)(EPh3)SC(Y)Y′R [Y?=?Y′?=?O; R?=?2-C6H4Cl (5), 4-C6H4Cl (6); Y?=?S, Y′?=?O; R?=?C6H4F (7), Y?=?Y′?=?S; R?=?Ph (8); E?=?P (a), As (b), Sb (c)] have been isolated and characterized by spectroscopic analysis (UV–Vis, IR, 1H, 31P NMR) and elemental analysis. The molecular structures of CpFe(CO)(PPh3)SCO2-2-C6H4Cl (5a) and its dicarbonyl parent CpFe(CO)2SCO2-2-C6H4Cl (1) have been determined by single crystal X-ray crystallographic studies.
Iron dithiocarbonate complexes: Structure of CpFe(CO)2SC(S)O-4-C6H4Cl
El-khateeb, Mohammad,Asali, Khalil J.,Lataifeh, Anas
, p. 1695 - 1699 (2008/10/09)
A group of dithiocarbonate iron complexes CpFe(CO)2SC(S)OAr (1) were prepared by the reaction of (μ-Sx)[CpFe(CO)2]2 with arylchlorothionoformates (Ar = Ph (1a), 4-C6H4Cl (1b), 4-C6H4F (1c), C6F5 (1d), 4-C6H4CH3 (1e)). The conversion of 1 into CpFe(CO)(κ2S,S-SC(S)OAr) (2), in which the dithiocarbonate ligand is bonded to the iron through the two S-atoms, can be achieved photolytically. The structure of CpFe(CO)2SC(S)O-4-C6H4Cl (1b) is reported.
