890660-77-2Relevant academic research and scientific papers
Three-step α-acylation of (E)-cinnamate esters with inversion of stereochemistry through formation and cleavage of carbon- pentamethylcyclopentadienyl bonds
Uemura, Minoru,Yorimitsu, Hideki,Oshima, Koichiro
, p. 408 - 409 (2007/10/03)
The reaction of cinnamate esters with lithium pentamethylcyclopentadienide in the presence of chlorodiethylaluminum provides the corresponding 1,4-adducts in high yield. The adducts undergo α-acylation reaction upon treatment with lithium diisopropylamide
