89104-03-0Relevant academic research and scientific papers
ACYCLIC STEREOSELECTION. 20. HIGH DIASTEREOFACIAL SELECTIVITY IN THE STANNIC CHLORIDE MEDIATED REACTIONS OF ALLYLSILANES WITH CHIRAL α- AND β-ALKOXY ALDEHYDES.
Kiyooka, Syun-ichi,Heathcock, Clayton H.
, p. 4765 - 4768 (1983)
Stannic chloride is an effective catalyst for the reaction of allylsilanes with chiral α- and β-alkoxy aldehydes.In the case of α-alkoxy aldehyde 1, the diastereofacial preference is outstanding (>35:1).With β-alkoxy aldehydes 5 and 6, selectivity lower, but still quite acceptable (7-12:1).
