89110-59-8Relevant academic research and scientific papers
Novel reaction course of thiiranes to vinyloxiranes: Reaction of benzyne with thiiranes and aldehydes
Okuma, Kentaro,Qu, Yuxuan,Nagahora, Noriyoshi
, p. 1294 - 1300 (2021/07/19)
Reaction of 2 molar amount of 2-(trimethylsilyl)phenyl triflate with thiiranes and aldehydes in the presence of CsF afforded vinyloxiranes in one-pot operation. Reaction of benzyne with thiiranes gave the corresponding alkenyl phenyl sulfides, which furth
Syntheses and synthetic applications of stannylated allylic alcohols
Kazmaier, Uli,Lucas, Simon,Klein, Manuela
, p. 2429 - 2433 (2007/10/03)
Allenyl carbinols undergo regioselective hydrostannation in the presence of MoBl3, a catalyst originally developed for the hydrostannation of alkynes, giving rise to allyl stannanes. These allyl stannanes can easily be converted into useful synthetic building blocks such as allyl iodides or vinyl epoxides.
Simple synthetic method of allyl- and vinyl-epoxides by allylation of carbonyl groups with allylic tins catalyzed by PbI2-HMPA
Shibata, Ikuya,Fukuoka, Shoji,Baba, Akio
, p. 533 - 534 (2007/10/03)
Allyl epoxides were prepared by the chemoseletive allylation at the carbonyl groups of a-bromo ketones with allylic tin, where PbI2-HMPA effected as a chemoselective catalyst. Moreover, vinyl epoxides were obtained in one pot procedure by the P
A FIRST EXAMPLE OF CATALYTIC YLIDE EPOXIDATION REACTION: FACILE SYNTHESIS OF VINYL EPOXIDES FROM ALDEHYDES CATALYZED BY DIISOBUTYL TELLURIDE
Zhou, Zhang-Lin,Shi, Li-Lan,Huang, Yao-Zeng
, p. 7657 - 7660 (2007/10/02)
In the presence of cesium carbonate, a variety of aldehydes can be epoxidized directly with allyl bromide at 50 deg C under solid-liquid phase transfer condition by use of a catalytic amount of diisobutyl telluride to afford vinyl epoxides in good yields
