89110-89-4Relevant academic research and scientific papers
Lewis acid catalyzed stereoselective hydrosilylation of ketones under the control of σ-π chelation
Asao, Naoki,Ohishi, Takeshi,Sato, Kenichiro,Yamamoto, Yoshinori
, p. 8195 - 8203 (2007/10/03)
Hydrosilylation of 2-methyl-1-phenyl-pentan-1-one with Et3SiH in the presence of catalytic amounts of B(C6F5)3 gave the anti-product with slight predominance over syn-product (syn/anti=1:1.5). In contrast, the s
A RING OPENING REACTION OF OXETANES WITH LITHIUM ACETYLIDES PROMOTED BY BORON TRIFLUORIDE ETHERATE
Yamaguchi, Masahiko,Nobayashi, Yukio,Hirao, Ichiro
, p. 4261 - 4266 (2007/10/02)
Several substituted oxetanes were treated with lithium acetylides in the presence of boron trifluoride etherate to give γ-hydroxyacetylenes.The reaction conditions were varied and several synthetic features of the present reaction were revealed.
THE ALKYNYLATION REACTION OF OXETHANES
Yamaguchi, Masahiko,Nobayashi, Yukio,Hirao, Ichiro
, p. 5121 - 5122 (2007/10/02)
γ-Hydroxyacetylenes were synthesized in high yields by the reaction of oxetanes with lithium acetylides in the presence of boron trifluoride etherate.
