89113-71-3Relevant academic research and scientific papers
Lewis Acid Induced Nucleophilic Substitution Reaction of β-Nitro Sulfides
Kamimura, Akio,Sasatani, Hiroyuki,Hashimoto, Toshihiro,Ono, Noboru
, p. 4998 - 5003 (2007/10/02)
The nitro group of β-nitro sulfides is readily substituted by an allyl or a cyano group or hydrogen on treatment with allyltrimethylsilane, cyanotrimethylsilane, or triethylsilane in the presence of an appropriate Lewis acid.The intramolecular Friedel-Cra
ALKENE CARBOSULPHENYLATION AND CARBOSELENYLATION: THE USE OF ALLYLTRIMETHYLSILANE AND O-SILYLATED ENOLATES.
Alexander, Rikki P.,Paterson, Ian
, p. 5911 - 5914 (2007/10/02)
Allyltrimethylsilane, as well as O-silylated enolates, can be alkylated by the PhSCl adducts of alkenes and vinyl ethers (1, X=SPh); the PhSeCl analogues (1, X=SePh), however, are less useful for alkylation purposes due to competing nucleophilic attack at selenium.
