89114-45-4 Usage
Uses
Used in Chemical Manufacturing:
2-Furancarboxaldehyde, 5-(1-hydroxycyclohexyl)-, oxime, (Z)is used as a building block for the production of various chemical compounds, including pesticides, pharmaceuticals, and organic synthesis. Its unique structure and properties make it a valuable component in the synthesis of other chemicals.
Used in Organic Chemistry Research:
2-Furancarboxaldehyde, 5-(1-hydroxycyclohexyl)-, oxime, (Z)is used in the field of organic chemistry for research purposes. Its potential biological activities and unique chemical properties make it an interesting subject for further study and exploration.
Used in Medical and Healthcare Research:
2-Furancarboxaldehyde, 5-(1-hydroxycyclohexyl)-, oxime, (Z)may possess certain biological activities, making it a potential candidate for medical and healthcare research. Its potential applications in this field are currently being explored and may lead to new discoveries and advancements in medicine.
Check Digit Verification of cas no
The CAS Registry Mumber 89114-45-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,9,1,1 and 4 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 89114-45:
(7*8)+(6*9)+(5*1)+(4*1)+(3*4)+(2*4)+(1*5)=144
144 % 10 = 4
So 89114-45-4 is a valid CAS Registry Number.
89114-45-4Relevant academic research and scientific papers
Reactions of Oxime Dianions with Electrophiles: An Attempt to Use Aldoximes as Acyl Anion Equivalents and the Synthesis of 2,5-Disubstituted Furans
Ager, David J.
, p. 2748 - 2759 (2007/10/02)
The oxime of benzaldehyde (3), when treated with n-butyl-lithium, gave a mixture of the vinyl-lithium (5) and benzonitrile (4).Despite its potential as an acyl anion equivalent, the dianion (5) could only be formed in moderate yield and was always accompanied by elimination products.Aliphatic aldoximes (1) gave the alkyl anion with n-butyl-lithium, but were only alkylated in the case of the Z-isomer.The oxime of furfuraldehyde (8) underwent deprotonation at the 5-position of the furan ring with n-butyllithium - N,N,N',N' - tetramethylethylenediamine in tetrahydrofuran.The resultant dianion (10) was reacted with a variety of electrophiles to give the 2,5-disubstituted furan (9).
THE SYNTHESIS OF 2,5-DISUBSTITUTED FURANS
Ager, David J.
, p. 5441 - 5444 (2007/10/02)
The dianion derived from the oxime of furfuraldehyde (1) reacts with electrophiles at the 5-position of the furan ring; subsequent hydrolysis of the oxime provides a useful method for the synthesis of 2,5-disubstituted furans.
