891202-96-3Relevant academic research and scientific papers
Intramolecularly donor-stabilized silenes Part 3. Synthesis and structure of 1-[2,6-bis(dimethylaminomethyl)phenyl]-1,2,2-tris(trimethylsilyl)silene
P?tter, Matthias,B?umer, Ute,Mickoleit, Martin,Kempe, Rhett,Oehme, Hartmut
, p. 261 - 266 (2001)
1-[2,6-Bis(dimethylaminomethyl)phenyl]-1,2,2-tris(trimethylsilyl)silene (9) was prepared by treatment of (dichloromethyl)tris-(trimethylsilyl)silane (3) with 2,6-bis(dimethylaminomethyl)phenyllithium (molar ratio 1:2). 9 is a crystalline compound, indefin
Intramolecularly donor-stabilized silenes: Part 6. the synthesis of 1-[2,6-bis(dimethylaminomethyl)phenyl]silenes and their reaction with aromatic aldehydes
B?umer, Ute,Reinke, Helmut,Oehme, Hartmut
, p. 229 - 239 (2007/10/03)
The intramolecularly donor-stabilized silenes ArR1SiC(SiMe 3)2 (3a-d) (3a: R1 = Me; 3b: R1 = t-Bu; 3c: R1 = Ph; 3d: R1 = SiMe3; Ar = 2,6-(Me2NCH2
