89121-17-5Relevant academic research and scientific papers
Reactivity of transition-metal-substituted phosphoranes: Spectroscopic and x-ray crystal structural study of the hydrolysis of pentacarbonyl-(2,2′-spirobi[1,3,2-benzodioxaphosphol-2-yl])manganese
Lattman, Michael,Anand, Badri N.,Chu, Shirley S. C.,Rosenstein, Robert D.
, p. 670 - 674 (2008/10/08)
The hydrolysis of the title compound is found to proceed according to the reaction (Chemical Equation Presented) The hydrolysis reactions in solution lead initially to two phosphorus-containing species, 2 and 3. 2 is found to rearrange to 3 and catechol in solution. The crystal structure of 2, (o-HOC6H4O)2P(O)Mn(CO)5, was determined, and it belongs to the tetragonal system with a space group of I41/a. The unit cell parameters are a = 25.145 (10) and c = 12.025 (5) ? and Z = 16. The phosphoryl oxygen is linked to two hydroxyl groups with one intramolecular and one intermolecular hydrogen bond.
SYNTHESIS AND REACTIVITY OF TRANSITION METAL-SUBSTITUTED PHOSPHORANES
Lattman, Michael,Anand, Badri N.,Chu, Shirley S. C.,Rosenstein, Robert R.
, p. 303 - 306 (2007/10/02)
The synthesis of , 1, by nucleophilic substitution of Cl- by Mn(CO)5- is described.The hydrolysis reactions of 1 lead to two compounds containing P-Mn bonds whose structures have been determined by x-ray crystallography.
