89162-97-0

Upstream product

• 75337-05-2 (+)-(R)-4-methyl-2-cyclohexene-1-one 
• 5524-05-0 (2R,5R)-5-isopropenyl-2-methylcyclohexanone 
• 33475-09-1 1,2-dimethyl-1-cyclohexen-4-one 
• 917-54-4 methyllithium 
• 62392-84-1 (+)-(R)-6-methylcyclohex-2-en-1-one 
• 89088-84-6 ((R)-4,5-Dimethyl-cyclohexa-1,5-dienyloxy)-trimethyl-silane 

Downstream Products

• 95529-81-0 Carbonic acid (3S,4R)-3,4-dimethyl-3-((S)-3-methyl-pent-4-enyl)-cyclohex-1-enyl ester methyl ester 
• 89088-85-7 (3S,4R)-3,4-dimethyl-3-<(3(R)-methyl-4-pentenyl)-1-cyclohexen-1-yl>carbonate 
• 179944-22-0 diethyl (+)-(4R)-(3,3,4-trimethylcyclohex-1-en-1-yl)phosphoric triester 
• 25436-90-2 kolavenic acid 
• 89088-87-9 (2R)-4-<(1S,6R)-1,6-dimethyl-2-methylene-3-oxocyclohexyl>-2-methyl-butanal 
• 89088-86-8 (3S,4R)-2-<(dimethylamino)methyl>-3,4-dimethyl-3-<(3(R)-methyl-4-pentenyl)>-1-cyclohexanone 
• 89105-98-6 methyl (4R)-2-bromo-6-<(1S,6R)-1,6-dimethyl-3-oxocyclohexyl>-4-methyl-2-hexenoate 
• 95529-83-2 (2S)-4-<(1S,6R)-1,6-dimethyl-2-methylene-3-oxocyclohexyl>-2-methyl-butanal 
• 95529-82-1 (3S,4R)-2-Dimethylaminomethyl-3,4-dimethyl-3-((S)-3-methyl-pent-4-enyl)-cyclohexanone 
• 26166-39-2 Ascochlorin 
• 85785-71-3 (2EZ,4E,1'R,2'R,6'R)-(-)-5-(1',2',6'-trimethyl-3'-oxocyclohexyl)-3-methyl-2,4-pentadien-1-ol 
• 85785-72-4 (2EZ,4E,1'R,2'R,6'R)-(-)-5-(1',2',6'-trimethyl-3'-oxocyclohexyl)-3-methyl-2,4-pentadienyl acetate 
• 85912-78-3 (2'E,4'E,1''R,2''R,6''R)-3-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-2,4-dimethoxy-6-methyl-1,4-cyclohexadiene 
• 99529-52-9 (2'E,4'E,1''R,2''R,6''R)-4-chloro-2-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>orcinol 

Relevant academic research and scientific papers

Asymmetric approach toward chiral cyclohex-2-enones from anisoles via an enantioselective isomerization by a new chiral diamine catalyst

A 3-step asymmetric approach toward the optically active chiral cyclohex-2-enones from anisoles has been developed. The crucial asymmetric induction step is an unprecedented catalytic enantioselective isomerization of β,γ-unsaturated cyclohex-3-en-1-ones

Improved enantioselective synthesis of natural striatenic acid and its methyl ester

This letter describes the improved and efficient enantioselective synthesis of natural striatenic acid, isolated from Cheilolejeunea serpentina, and its methyl ester starting from a readily available enantiopure building block.

Syntheses and absolute configurations of the marine sponge purines (+)-agelasimine-A and (+)-agelasimine-B

The first total syntheses of (+)-agelasimine-A and (+)-agelasimine-B, adenine-related bicyclic diterpenoids isolated from the marine sponge Agelas mauritiana, have been achieved via a highly stereoselective route. On the basis of the present results, the absolute configurations of both alkaloids have been defined as shown in stereoformulas (+)-1a and (+)-1b, respectively.

Asymmetric Synthesis of Clerodane Diterpenoids: Total Synthesis of (-)-Methyl Kolavenate

The asymmetric synthesis of (8R,9S,10R)-4,8,9-trimethyl-9-vinyl-Δ4-3-octalone, a versatile intermediate for the syntheses of both trans- and cis-neo-clerodane diterpenoids, has been achieved by extension of Ender's asymmetric alkylation, and its utility is exemplified by the total synthesis of (-)-methyl kolavenate, the first example of a clerodane diterpenoid in optically active form.

A Notable Stereochemical Variation in the 2 + 2 + 2 Annulation Reaction

A rapid entry to the epiaflavinine ring system is described.