89218-21-3

Basic information

• Product Name: (S)-1-[(R)-((S)-Benzenesulfinylmethyl)-ethoxy-phosphinoyl]-pyrrolidine-2-carboxylic acid ethyl ester
• CAS NO: 89218-21-3
• Molecular Weight: 373.41
• Mol File: 89218-21-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-[(R)-((S)-Benzenesulfinylmethyl)-ethoxy-phosphinoyl]-pyrrolidine-2-carboxylic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-[(R)-((S)-Benzenesulfinylmethyl)-ethoxy-phosphinoyl]-pyrrolidine-2-carboxylic acid ethyl ester(89218-21-3)
• EPA Substance Registry System: (S)-1-[(R)-((S)-Benzenesulfinylmethyl)-ethoxy-phosphinoyl]-pyrrolidine-2-carboxylic acid ethyl ester(89218-21-3)

Safety Data

• Hazardous Substances Data: 89218-21-3(Hazardous Substances Data)

Upstream product

• 89218-24-6 (S)-1-((S)-Ethoxy-phenylsulfanylmethyl-phosphinoyl)-pyrrolidine-2-carboxylic acid ethyl ester 

Downstream Products

• 89218-22-4 (S)-1-[(R)-(1-Benzenesulfinyl-propyl)-ethoxy-phosphinoyl]-pyrrolidine-2-carboxylic acid ethyl ester 
• 89218-22-4 (S)-1-[(S)-(1-Benzenesulfinyl-propyl)-ethoxy-phosphinoyl]-pyrrolidine-2-carboxylic acid ethyl ester 
• 89299-89-8 1-[(E)-2-((S)-Benzenesulfinyl)-vinyl]-4-chloro-benzene 
• 89299-86-5 (+)-(R)_S-phenyl vinyl sulfoxide 
• 20451-53-0 (-)-(S)_S-phenyl vinyl sulfoxide 
• 89299-88-7 C₁₄H₁₂OS 
• 89299-87-6 (S)-(E)-(2-(phenylsulfinyl)vinyl)benzene 

Relevant articles and documents

PREPARATION OPTICALLY ACTIVE α,β-UNSATURATED PHOSPHONATES AND SULFOXIDES FROM PHENYLSULFENYLMETHANEPHOSPHONATES

The first preparation of optically active α,β-unsaturated phosphonyl compounds from chiral phenylsulfenylmethanephosphonates 1 and 2 has been described.The optically active α,β-unsaturated sulfoxides have also been prepared by the Emmons-Horner reaction of phenylsulfinylmethanephosphonamidate 4 with several aldehydes.KEYWORDS - chiral α,β-unsaturated phosphonate; chiral α,β-unsaturated sulfoxide; absolute configuration; chirality transfer reaction