892402-16-3

Upstream product

• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 133697-34-4 2,6-anhydro-3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-hept-1-enitol 
• 30608-21-0 1-O-trimethylsilyl-2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 137344-41-3 3,4,5,7-tetra-O-benzyl-1-deoxy-α-D-gluco-hept-2-ulopyranose 
• 140658-55-5 2-O-acetyl-3,4,5,7-tetra-O-benzyl-1-deoxy-α-D-gluco-hept-2-ulopyranose 

Relevant academic research and scientific papers

Development of ketoside-type analogues of trehalose by using α-stereoselective O-glycosidation of ketose

The stereoselective synthesis of ketoside-type analogues of trehalose is described. O-Glycosidation of hept-2-ulopyranose with trimethylsilyl α-pyranoside promoted by trimethylsilyl trifluoromethanesulfonate afforded α-ketopyranosyl α-aldopyranosides excl

Synthesis of trehalose mimics by bismuth(III) triflate or bis(trifluoromethane)sulfonimide-catalyzed 1-C-methyl-d-hexopyranosylation

We investigated the ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-d-hexopyranoses with the benzylated d-aldohexopyranoses in order to produce novel non-reducing disaccharides as trehalose mimics. It was found that 5 mol % of bismuth(III) triflat