89279-55-0

Basic information

• Product Name: (2S*,1'S*)-2-<(1'-benzyloxy)propyl>-6-<4'-((tert-butyldimethylsilyl)oxy)butyl>-2,3-dihydro-4H-pyran-4-one
• Synonyms: (2S*,1'S*)-2-<(1'-benzyloxy)propyl>-6-<4'-((tert-butyldimethylsilyl)oxy)butyl>-2,3-dihydro-4H-pyran-4-one
• CAS NO: 89279-55-0
• Molecular Weight: 432.676
• Mol File: 89279-55-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S*,1'S*)-2-<(1'-benzyloxy)propyl>-6-<4'-((tert-butyldimethylsilyl)oxy)butyl>-2,3-dihydro-4H-pyran-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2S*,1'S*)-2-<(1'-benzyloxy)propyl>-6-<4'-((tert-butyldimethylsilyl)oxy)butyl>-2,3-dihydro-4H-pyran-4-one(89279-55-0)
• EPA Substance Registry System: (2S*,1'S*)-2-<(1'-benzyloxy)propyl>-6-<4'-((tert-butyldimethylsilyl)oxy)butyl>-2,3-dihydro-4H-pyran-4-one(89279-55-0)

Safety Data

• Hazardous Substances Data: 89279-55-0(Hazardous Substances Data)

Upstream product

• 91860-77-4 ((E)-(S)-1-Ethyl-but-2-enyloxymethyl)-benzene 
• 80928-04-7 (S)-(-)-2-Benzyloxybutyraldehyde 
• 91860-83-2 (E)-8-(tert-Butyl-dimethyl-silanyloxy)-2-triethylsilanyloxy-octa-1,3-diene 
• 91860-82-1 (2S*,1'S*,6R*)-2-<(1'-benzyloxy)propyl>-4-<(triethylsilyl)oxy>-6-<4'-((tert-butyldimethylsilyl)oxy)butyl>-2,3-dihydro-6H-pyran 
• 89279-49-2 2-(benzyloxy)butanal 

Relevant articles and documents

Chelation-Controlled Facially Selective Cyclocondensation Reactions of Chiral Alkoxy Aldehydes: Syntheses of a Mouse Androgen and of a Carbon-Linked Disaccharide

Magnesium bromide in tetrahydrofuran catalyzes the cycloaddition of a variety of chiral alkoxy aldehydes with activated butadienes.The stereochemistry of these products is such that they can be rationalized as arising from a reacting conformer in which th