892859-15-3Relevant academic research and scientific papers
In situ preparation of rhodium/N-heterocyclic carbene complexes and use for addition of arylboronic acids to aldehydes
Kilincarslan, Rafet,Yigit, Murat,Oezdemir, Ismail,Cetinkaya, Engin,Cetinkaya, Bekir
, p. 69 - 73 (2008/09/18)
(Chemical Equation Presented) The in situ prepared three component system [RhCl(COD)]2/imidazolidinium salts (2, 4) and KOBut catalyses the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields. Four novel 1,3-dialkylimidazolidinium (2-4) salts as NHC precursors were synthesized from N,N′-dialkylethylenediamine.
The Synthesis, Structural Characterization and Conformational Analysis of (1,3-Bis(2-methyl-4-diethylaminophenyl)imidazolidin-2-ylidene)chloro(1, 5-cyclooctadiene)rhodium(I)
Karabiyik, Hasan,Kilin?arslan, Rafet,Aygün, Muhittin,?etinkaya, Bekir,Büyükgüng?r, Orhan
, p. 837 - 842 (2007/10/03)
A four-coordinated Rh(I) complex with a new heterocyclic carbene ligand, functionalized by amino donor pendants, 4, was synthesized and characterized by elemental analyses, NMR and IR spectroscopy, and the molecular structure of the title compound has bee
