892867-41-3

Upstream product

• 108-94-1 cyclohexanone 
• 892867-39-9 (2R,3S,4S)-2-Cyclohex-1-enyl-2,3-dimethyl-5-trityloxy-pentane-1,4-diol 
• 892867-38-8 (3R,4S,5S)-3-Cyclohex-1-enyl-3,4-dimethyl-5-trityloxymethyl-dihydro-furan-2-one 
• 892867-40-2 ((1S,2S,3R)-4-Benzyloxy-3-cyclohex-1-enyl-2,3-dimethyl-1-trityloxymethyl-butoxy)-tert-butyl-dimethyl-silane 

Downstream Products

• 156980-57-3 (-)-tetrodecamycin 
• 892867-42-4 (S)-2-[(1R,2S,3S)-1-Benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-1,2-dimethyl-4-trityloxy-butyl]-cyclohexanone 
• 892867-47-9 (E)-2-((3aR,4S,5S,6R,6aS,10aS)-6-Benzyloxymethyl-2,2,5,6-tetramethyl-octahydro-naphtho[1,8a-d][1,3]dioxol-4-yloxy)-but-2-enedioic acid diethyl ester 
• 892867-45-7 (1R,2S,3S,4R,4aS,8aS)-4-Benzyloxymethyl-2-(tert-butyl-dimethyl-silanyloxy)-3,4-dimethyl-octahydro-naphthalene-1,8a-diol 
• 892867-46-8 (3aR,4S,5S,6R,6aS,10aS)-6-Benzyloxymethyl-2,2,5,6-tetramethyl-octahydro-naphtho[1,8a-d][1,3]dioxol-4-ol 
• 892867-43-5 (R)-2-[(1R,2S,3S)-1-Benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-1,2-dimethyl-4-trityloxy-butyl]-cyclohexanone 

Relevant academic research and scientific papers

The first total synthesis of a tetracyclic antibiotic, (-)-tetrodecamycin

(-)-Tetrodecamycin (1) has been synthesized from optically active butenolide through stereoselective SmI2-mediated pinacol cyclization and newly developed deoxygenation.