89332-70-7Relevant academic research and scientific papers
EFFICIENT ASYMMETRIC INDUCTION VIA COORDINATION OF CHIRAL DIAMINE TO TIN(II) ENOLATE: A HIGHLY ENANTIOSELECTIVE SYNTHESIS OF 2-SUBSTITUTED MALATES
Stevens, Rodney W.,Mukaiyama, Teruaki
, p. 1799 - 1802 (1983)
In the presence of chiral diamine, (2S)-1-methyl-2-pyrrolidine, the tin(II) enolate of 3-acetylthiazolidine-2-thione reacts with various α-ketoesters to afford the corresponding aldol-type products, generally, in greater than 95 percent enantiomeric excess.
