893409-97-7Relevant academic research and scientific papers
Experimental and computational studies on the C-H amination mechanism of tetrahydrocarbazoles via hydroperoxides
Gulzar, Naeem,Jones, Kevin Mark,Konnerth, Hannelore,Breugst, Martin,Klussmann, Martin
supporting information, p. 3367 - 3376 (2015/03/05)
The acid-catalyzed reactions of photochemically generated tetrahydrocarbazole peroxides with anilines have been studied experimentally and computationally to identify the underlying reaction mechanism. The kinetic data indicate a reaction order of one in
Aerobic C-H amination of tetrahydrocarbazole derivatives via photochemically generated hydroperoxides
Gulzar, Naeem,Klussmann, Martin
, p. 4516 - 4520 (2013/08/23)
A Bronsted acid catalyzed C-H functionalization via Intermediate PeroxideS (CHIPS), generated photochemically, allows the oxidative coupling of indole derivatives with a variety of nitrogen nucleophiles. The reaction can be performed in one pot and requires only visible light, elemental oxygen, a Bronsted acid and a photosensitizer. The method can be applied to an efficient synthesis of some biologically active compounds. The Royal Society of Chemistry 2013.
