89366-17-6Relevant academic research and scientific papers
Application of a Lanthanide Shift Reagent in 17O N.M.R. Spectroscopy to determine the Stereochemical Course of Oxidation of Cyclic Sulphite Diesters to Cyclic Sulphate Diesters with Ruthenium Tetroxide
Lowe, Gordon,Salamone, Salvatore J.
, p. 1392 - 1394 (1983)
Cyclic sulphite diesters are rapidly oxidized to cyclic sulphate diesters with ruthenium tetroxide in good yield; diastereotopically labelled cyclic sulphate diesters obtained by oxidation of diastereoisomeric cyclic sulphite diesters with ruthenium tetroxide are shown, by the effect of a lanthanide shift reagent on their 17O n.m.r. signals, to be formed with retention of configuration at sulphur.
