893734-25-3Relevant academic research and scientific papers
Visual synchronous exchange of metal nodes and counteranions constituting a cobalt(II) coordination polymer
Wang, Jian-Cheng,Liu, Qi-Kui,Ma, Jian-Ping,Huang, Fang,Dong, Yu-Bin
, p. 10791 - 10793 (2014)
A solid-state simultaneous exchange of metal nodes and counteranions based on a cobalt(2+) coordination polymer is reported for the first time. The ion-exchange process is visual, and the structural integrity of the cobalt(2+) coordination polymer is maintained during the ion-exchange process.
A “universal” catalyst for aerobic oxidations to synthesize (hetero)aromatic aldehydes, ketones, esters, acids, nitriles, and amides
Bartling, Stephan,Beller, Matthias,Chandrashekhar, Vishwas G.,Jagadeesh, Rajenahally V.,Rabeah, Jabor,Rockstroh, Nils,Senthamarai, Thirusangumurugan
supporting information, p. 508 - 531 (2022/02/11)
Functionalized (hetero)aromatic compounds are indispensable chemicals widely used in basic and applied sciences. Among these, especially aromatic aldehydes, ketones, carboxylic acids, esters, nitriles, and amides represent valuable fine and bulk chemicals, which are used in chemical, pharmaceutical, agrochemical, and material industries. For their synthesis, catalytic aerobic oxidation of alcohols constitutes a green, sustainable, and cost-effective process, which should ideally make use of active and selective 3D metals. Here, we report the preparation of graphitic layers encapsulated in Co-nanoparticles by pyrolysis of cobalt-piperazine-tartaric acid complex on carbon as a most general oxidation catalyst. This unique material allows for the synthesis of simple, functionalized, and structurally diverse (hetero)aromatic aldehydes, ketones, carboxylic acids, esters, nitriles, and amides from alcohols in excellent yields in the presence of air.
A general Suzuki cross-coupling reaction of heteroaromatics catalyzed by nanopalladium on amino-functionalized siliceous mesocellular foam
Bratt, Emma,Verho, Oscar,Johansson, Magnus J,Baeckvall, Jan-Erling
, p. 3946 - 3954 (2014/05/20)
Suzuki-Miyaura cross-coupling reactions of heteroaromatics catalyzed by palladium supported in the cavities of amino-functionalized siliceous mesocellular foam are presented. The nanopalladium catalyst effectively couples not only heteroaryl halides with
