89482-98-4Relevant academic research and scientific papers
Silver(I) Ion Mediatied Desulfurization-Condensation of Thiocarbonyl Compounds with Several Nucleophiles
Shibuya, Isao,Taguchi, Yoichi,Tsuchiya, Tohru,Oishi, Akihiro,Katoh, Eisaku
, p. 3048 - 3052 (2007/10/02)
The desulfurization-condensation reaction was investigated in the presence of silver(I) salt for several kinds of thiocarbonyl compounds with nucleophiles.Such thiocarbonyl compounds as 4,4'-bis(dimethylamino)thiobenzophenone, ethylene trithiocarbonate, and N-(thiobenzoyl)morpholine react with malononitrile or other active methylene compounds in the presence of silver trifluoroacetate to afford the corresponding olefinic compounds together with silver sulfide.This reaction of thiocarbonyl compounds with some other nucleophiles such as aniline derivatives and ethylene glycol, has also afforded imines and 1,3-dioxolane derivatives.
Ring Opening of N-(Tetraalkylamidinio)pyridinium Salts by Anions of CH-Acidic Methylene Compounds
Feith, Bernhard,Weber, Hans-Martin,Maas, Gerhard
, p. 3276 - 3296 (2007/10/02)
N-Carbeniopyridinium salts 2, 4, 14, and 18 offer three sites to nucleophilic attack; depending on the reactants, all three modes have been realized.With anions of CH-acidic methylene compounds, α-attack at the pyridinium ring followed by ring opening leads to azahexamethine merocyanines (8, 15, 23).In some cases, kinetically controlled reactions yield 1,4-dihydropyridines which isomerize thermally to give 1,2-dihydropyridines which undergo ring opening spontaneously.Also, nucleophilic attack at the cationic substituent of the N-carbeniopyridinium salts is possible as is indicated by the formation of push-pull olefins 11, 16 and of enol ether 12.
Mass Spectra of Dicyanomethylene Derivatives of Benzophenone Analogs
Wang, Ching-Bore,Her, Guor-Rong,Watson, J. Throck
, p. 457 - 461 (2007/10/02)
The dicyanomethylene derivative of a benzophenone analog significantly alters the fragmentation pattern observed during electron impact ionization of the underivatized parent compound.A double bond connecting the dicyanomethylene moiety to the parent comp
