89503-46-8

Upstream product

• 128011-34-7 6-benzyloxy-4-hydroxymethylhex-4E-en-1-al ethyleneacetal 
• 128011-35-8 6-benzyloxy-4-methylhex-4Z-en-1-al ethyleneacetal 
• 116187-18-9 5,5-Ethylenedioxy-2-trimethylsilylpentanal tert-butylimine 
• 116187-17-8 5,5-Ethylenedioxypentanal tert-butylimine 
• 125556-29-8 (4E,8Z)-8-Benzyloxy-4-hydroxymethyl-8-methyl-4,8-decadienal ethylene acetal 
• 116187-19-0 6-benzyloxy-4-formylhex-4E-en-1-al ethyleneacetal 
• 116187-18-9 2-trimethylsilyl-5,5-ethylenedioxypentan-1-al tert-butylimine 
• 116187-17-8 5,5-ethylenedioxypentan-1-al tert-butylimine 
• 19790-60-4 3-Benzyloxypropanal 
• 55802-99-8 (Z)-6-(benzyloxy)-4-methylhex-4-enal 
• 90659-87-3 (6Z,10Z)-12-Benzyloxy-3-bromo-2,6,10-trimethyl-dodeca-6,10-dien-2-ol 
• 90659-90-8 (6Z,10Z)-12-Benzyloxy-2,6,10-trimethyl-dodeca-6,10-diene-2,3-diol 
• 90659-89-5 3-((3Z,7Z)-9-Benzyloxy-3,7-dimethyl-nona-3,7-dienyl)-2,2-dimethyl-oxirane 
• 68268-89-3 (Z,Z)-farnesyl benzyl ether 

Downstream Products

• 89503-39-9 11-formyl-3,7,15,19,23,27-hexamethyloctaeicosa-2Z,6Z,10E,14E,18E,22E,26-hepten-1-ol benzyl ester 
• 92464-84-1 (4Z,8Z)-10-Benzyloxy-4,8-dimethyl-deca-4,8-dien-1-ol 
• 128011-37-0 benzyl ether of 3,7,15,19,23-pentamethyl-11-hydroxymethyltetraeicosa-2Z,6Z,10E,14Z,18Z,22-hexaen-1-ol 
• 128011-38-1 benzyl ether of 3,7,11,15,19,23-hexamethyltetraeicosa-2Z,6Z,10Z,14Z,18Z,22-hexaen-1-ol 
• 15639-69-7 solanesol 
• 92464-88-5 (2Z,6Z,10Z)-12-Benzyloxy-2,6,10-trimethyl-dodeca-2,6,10-trien-1-ol 
• 92464-91-0 1-((2Z,6Z,10Z,14Z,18Z,22Z,26E,30E)-1-Benzyloxy-3,7,11,15,19,23,27,31,35-nonamethyl-hexatriaconta-2,6,10,14,18,22,26,30,34-nonaene-13-sulfonyl)-4-methyl-benzene 
• 92464-86-3 ((4Z,8Z)-10-Benzyloxy-4,8-dimethyl-deca-4,8-dienyl)-triphenyl-phosphonium; iodide 
• 92542-08-0 1-((2Z,6Z,10Z,14Z,18Z,22E,26E)-1-Benzyloxy-3,7,11,15,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaene-9-sulfonyl)-4-methyl-benzene 
• 92542-06-8 1-((6E,10E,14Z,18Z,22Z)-24-Benzyloxy-2,6,10,14,18,22-hexamethyl-tetracosa-2,6,10,14,18,22-hexaene-12-sulfonyl)-4-methyl-benzene 
• 5905-42-0 betulaprenol-8 
• 92542-76-2 1-((2Z,6Z,10Z,14E,18E)-3,7,11,15,19,23-Hexamethyl-tetracosa-2,6,10,14,18,22-hexaene-1-sulfonyl)-4-methyl-benzene 
• 92464-87-4 2-((2Z,6Z,10Z)-12-Benzyloxy-2,6,10-trimethyl-dodeca-2,6,10-trienyloxy)-tetrahydro-pyran 
• 101660-64-4 (2Z,6Z,10Z)-12-Benzyloxy-2,6,10-trimethyl-dodeca-2,6,10-trienal 

Relevant academic research and scientific papers

SYNTHESIS OF MODIFIED HEXAPRENOL WC5OH FROM GLUTARALDEHYDE DERIVATIVES

A new procedure was developed for building linear Z-isoprenoids from glutaraldehyde derivatives as nonisoprenoid precursors, and is illustrated by the synthesis of hexaprenol WC5OH.

Glutaraldehyde Derivatives as Building Blocks for Stereoselective (Z)-C5 Elongation of a Regular Isoprenoid Chain

5,5-Ethylenedioxypentanal and its tert-butylimine may serve as versatile non-isoprenoid synthons for the construction of a regular cisoid terpenoid chain using the controlled crossed aldol condensation methodology.

GENERAL METHOD OF STEREOSPECIFIC SYNTHESIS OF NATURAL POLYPRENOLS. SYNTHESIS OF BETULAPRENOL-6, -7, -8, AND -9

A stereoselective synthesis of (Z,Z,Z)-12-benzyloxy-1-chloro-2,6,10-trimethyldodeca-2,6,10-triene was achieved starting from (Z,Z)-farnesol.All the components of betulaprenols were synthesized using the C15 block 3 and its lower homologue (C10 block) as t

NOVEL APPROACH TO THE STEREOSELECTIVE SYNTHESIS OF POLYPRENOLS VIA DIRECTED ALDOL CONDENSATION. PREPARATION OF HEPTAPRENOLS ωtttcccOH AND ωtttcctOH.

New convenient and stereoselective route to linear isoprenoids including the construction of Z-trisubstituted double bond is elaborated based on directed aldol condensation.