895140-03-1Relevant articles and documents
Synthesis of fullerene-substituted oligo(phenylenebutadiyndiyl)
de la Cruz, Juan Luis Delgado,Hahn, Uwe,Nierengarten, Jean-Fran?ois
, p. 3715 - 3718 (2006)
A diethynylbenzene monomer substituted with two fullerene moieties has been prepared, and its oligomerization performed in the presence of phenylacetylene as end-capping reagent afforded the corresponding end-capped mono- and di-mer with an oligo(phenylenebutadiyndiyl) (OPB) conjugated backbone substituted with two and four fullerene subunits, respectively.
Phenylene vinylene platinum(II) acetylides with prodigious two-photon absorption
Dubinina, Galyna G.,Price, Randi S.,Abboud, Khalil A.,Wicks, Geoffrey,Wnuk, Pawel,Stepanenko, Yuriy,Drobizhev, Mikhail,Rebane, Aleksander,Schanze, Kirk S.
supporting information, p. 19346 - 19349 (2013/02/21)
The linear and nonlinear optical properties of a series of linear and cross-conjugated platinum(II) acetylide complexes that contain extended p-(phenylene vinylene) chromophores are reported. The complexes exhibit very high femtosecond two-photon absorption (2PA) cross section values (σ2 up to 10 000 GM), as measured by nonlinear transmission (NLT) and two-photon excited fluorescence (2PEF) methods. The large 2PA cross sections span a broad range of wavelengths, 570-810 nm, and they overlap with the triplet excited state absorption. Spectral coincidence of high cross section 2PA and triplet absorption is a key feature giving rise to efficient dual-mode optical power limiting (OPL).