89525-54-2Relevant academic research and scientific papers
PALLADIUM ASSISTED ORGANIC REACTIONS. VII. THE PREPARATION OF CYCLOPALLADATED PRIMARY AND SECONDARY BENZYLAMINES
Clark, P. W.,Dyke, S. F.
, p. 389 - 396 (2007/10/02)
A new method is described for the preparation of cyclopalladated benzylamines, involving the reaction of the ortho-bromobenzylamines with bis(dibenzylideneacetone)palladium(0).By using this method cyclopalladated complexes of simple primary and secondary benzylamines have been obtained for the first time.These complexes have been fully characterised as either the monomeric bromo(benzylamine-6-C,N)triphenylphosphinepalladium(II) derivatives or as the corresponding acetyl-acetonates. 1H and 13C NMR spectral data have been obtained and, in most cases, full assignments have been made.
