89538-96-5

Basic information

• Product Name: Benzoic acid, 4-(chlorosulfinyl)-, methyl ester
• CAS NO: 89538-96-5
• Molecular Formula: C8H7ClO3S
• Molecular Weight: 218.661
• Mol File: 89538-96-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-(chlorosulfinyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-(chlorosulfinyl)-, methyl ester(89538-96-5)
• EPA Substance Registry System: Benzoic acid, 4-(chlorosulfinyl)-, methyl ester(89538-96-5)

Safety Data

• Hazardous Substances Data: 89538-96-5(Hazardous Substances Data)

Upstream product

• 69812-51-7 4-chlorosulfonyl-benzoic acid methyl ester 
• 110955-49-2 p-methoxycarbonylbenzenesulfinic acid 

Downstream Products

• 89538-98-7 S-(4-methoxycarbonylphenyl)-N-tosylsulfonimidoyl fluoride 
• 187342-38-7 C₁₅H₁₄ClN₃O₄S 
• 1027423-52-4 C₁₅H₁₂Cl₂N₂O₄S 
• 187342-33-2 C₁₅H₁₃ClN₂O₄S 
• 1027081-25-9 4-Isocyanatosulfinyl-benzoic acid methyl ester 
• 110955-54-9 4-Isopropylidenesulfamoyl-benzoic acid methyl ester 

Relevant articles and documents

THERMAL Z,E-ISOMERIZATION OF IMINES. VI. N-ARYLSULFONYLIMINES OF ACETONE AND 2,6-DI-tert-BUTYL-1,4-BENZOQUINONE

The thermal topomerization of acetone N-arylsulfonylimines and 2,6-di-tert-butyl-1,4-benzoquinone N-arylsulfonyl-4-monoimines was studied by the dynamic PMR method.The inversion mechanism of the topomerization of the N-arylsulfonylimines was established on the basis of an investigation into the electronic and steric effects of substituents at the sulfur atom on the sizes of the barriers to topomerization.The effect of nN-3dS and nN-?c-s* interactions and the induction effect of the arylsulfonyl group on the sizes of the barriers to inversion at the nitrogen atom are considered.The reduction of the barriers to inversion in the N-arylsulfonylimines with increase in the electron-withdrawing characteristics of the para substituents in the aryl ring is largely determined by the increase in the nN-3dS interaction.