895532-59-9Relevant academic research and scientific papers
Pestalotiopsin A. Enantioselective construction of potential building blocks derived from antipodal cyclobutanol intermediates
Paquette, Leo A.,Parker, Gregory D.,Tei, Takahiro,Dong, Shuzhi
, p. 7124 - 7134 (2008/02/11)
(Chemical Equation Presented) D-Glyceraldehyde acetonide has been used as the starting point for accessing the enantiomeric cyclobutanols 11 in optically pure condition. The dextrorotatory enantiomer has been transformed in five steps into the [3.2.0] bic
In pursuit of pestalotiopsin A via zirconocene-mediated ring contraction
Dong, Shuzhi,Parker, Gregory D.,Tei, Takahiro,Paquette, Leo A.
, p. 2429 - 2431 (2007/10/03)
An asymmetric route from the epimeric β-hydroxy esters 4 and 5 to the densely functionalized (+)-10 and (-)-10, respectively, is described. Either cyclobutanol can be made available as the predominant product. The levorotatory antipode has been transforme
