89563-36-0

Basic information

• Product Name: Thiourea, N-(2,2-dimethylpropyl)-N-methyl-
• Synonyms: Thiourea, N-(2,2-dimethylpropyl)-N-methyl-
• CAS NO: 89563-36-0
• Molecular Formula: C7H16N2S
• Molecular Weight: 160.28
• Mol File: 89563-36-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Thiourea, N-(2,2-dimethylpropyl)-N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Thiourea, N-(2,2-dimethylpropyl)-N-methyl-(89563-36-0)
• EPA Substance Registry System: Thiourea, N-(2,2-dimethylpropyl)-N-methyl-(89563-36-0)

Safety Data

• Hazardous Substances Data: 89563-36-0(Hazardous Substances Data)

Upstream product

• 6972-05-0 1,1-dimethyl-2-thiourea 

Relevant articles and documents

2-(N,N-Disubstituted Amino)thiazoles with Electron-withdrawing Groups at Position 5: Prepaeation and Investigation on Structural Features

A convenient procedure for preparing N-mono- and NN-di-substituted cyanamides from cyanogen bromide has been developed.N,N-Disubstituted thioureas, obtained from the cyanamides, were condensed with α-bromo-α-cyanoketones to give 5-cyano-2-(N,N-disubstituted amino)thiazoles and with α-bromo-ketones to give 2-(N,N-disubstituted amino)thiazoles.Substitution in the latter products afforded 5-trifluoroacetyl- and 5-nitro-2-(N,N-disubstituted amino)thiazoles; nitration is greatly facilitated by the presence of a 4-aryl group.The average values of the barriers of rotation of the barriers to rotation of the 2-NR2 groups (ΔG298) in the 5-substituted thiazoles were established by variable temperature 1H n.m.r. spectrometry to be 57.4 kJ mol -1 (5-NO2), 56.2 (5-COCF3), and 51.5 (5-CN).I.r. examination showed that the 5-trifluoroacetyl compounds adopt one rotational form preferentially; this is probably the carbonyl O,S-syn-conformation.