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Benzenebutanoic acid, a-(methoxymethoxy)-a-methyl-, (methylthio)methyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

89578-13-2

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89578-13-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 89578-13-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,9,5,7 and 8 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 89578-13:
(7*8)+(6*9)+(5*5)+(4*7)+(3*8)+(2*1)+(1*3)=192
192 % 10 = 2
So 89578-13-2 is a valid CAS Registry Number.

89578-13-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name (methylthio)methyl 2-(methoxymethoxy)-2-methyl-4-phenylbutanoate

1.2 Other means of identification

Product number -
Other names 2-Methoxymethoxy-2-methyl-4-phenyl-butyric acid methylsulfanylmethyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:89578-13-2 SDS

89578-13-2Relevant academic research and scientific papers

Total Synthesis of a Macrocyclic Pyrrolizidine Alkaloid, (+/-)-Integerrimine, Utilizing an Activable Protecting Group

Narasaka, Koichi,Sakakura, Toshiyasu,Uchimaru, Tadafumi,Guedin-Vuong, Denis

, p. 2954 - 2961 (1984)

A new esterification reaction has been developed utilizing a (methylthio)methyl (MTM) group as an activable protecting group of carbocyclic acid.A total synthesis of a 12-membered pyrrolizidine alkaloid, (+/-)-integerrimine (1), has been achieved by applying the above method to formation of the macrocyclic bislactone skeleton.The acid anhydride (16b) of the integerrinecic acid derivative was coupled with lithium alkoxide of retronecine silyl ether (5b) in the presence of DMAP to afford the α,β-unsaturated ester.Oxidation of the MTM group afforded an active (methylsulfonyl)methyl ester (28b), which cyclized to give the macrocyclic bislactone 29.

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