89590-30-7Relevant articles and documents
SELECTIVE HYDROESTERIFICATION OF ALKYNES TO MONO- OR DIESTERS
Alper, Howard,Despeyroux, Bertrand,Woell, James B.
, p. 5691 - 5694 (2007/10/02)
Terminal alkynes (including acetylene) undergo regioselective hydroesterification to unsaturated cis-diesters using PdCl2, CuCl2, HCl, alcohol, carbon monoxide, and oxygen; cis-monoesters are formed from internal alkynes.These reactions are complete within two hours at room temperature and atmospheric pressure.