89610-94-6

Basic information

• Product Name: 1,3,5-Cycloheptatriene, 7-[4-(1,1-dimethylethyl)phenyl]-
• CAS NO: 89610-94-6
• Molecular Formula: C17H20
• Molecular Weight: 224.346
• Mol File: 89610-94-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3,5-Cycloheptatriene, 7-[4-(1,1-dimethylethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Cycloheptatriene, 7-[4-(1,1-dimethylethyl)phenyl]-(89610-94-6)
• EPA Substance Registry System: 1,3,5-Cycloheptatriene, 7-[4-(1,1-dimethylethyl)phenyl]-(89610-94-6)

Safety Data

• Hazardous Substances Data: 89610-94-6(Hazardous Substances Data)

Upstream product

• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 27081-10-3 tropylium tetrafluoroborate 

Relevant articles and documents

Gold Catalysts Can Generate Nitrone Intermediates from a Nitrosoarene/Alkene Mixture, Enabling Two Distinct Catalytic Reactions: A Nitroso-Activated Cycloheptatriene/Benzylidene Rearrangement

Gold-catalyzed reactions of cycloheptatrienes with nitrosoarenes yield nitrone derivatives efficiently. This reaction sequence enables us to develop gold-catalyzed aerobic oxidations of cycloheptatrienes to afford benzaldehyde derivatives using CuCl and nitrosoarenes as co-catalysts (10-30 mol %). Our density functional theory calculations support a novel nitroso-activated rearrangement, tropylium → benzylidene. With the same nitrosoarenes, we developed their gold-catalyzed [2 + 2 + 1]-annulations between nitrosobenzene and two enol ethers to yield 5-alkoxyisoxazolidines using 1,4-cyclohexadienes as hydrogen donors.