89618-17-7

Usage

InChI:InChI=1/C18H14O/c1-2-4-12-10-16-13(9-11(12)3-1)5-6-15-14(16)7-8-17-18(15)19-17/h1-6,9-10,17-18H,7-8H2/t17-,18+/m0/s1

Upstream product

• 148260-36-0 (-)-(3S,4S)-trans-3-bromo-1,2,3,4-tetrahydrobenzanthracen-4-ol 
• 148260-35-9 (+)-(3R,4R)-trans-3-bromo-1,2,3,4-tetrahydrobenzanthracen-4-ol 
• 148190-91-4 (-)-(3R,4R)-trans-3-bromo-4-menthyloxyacetoxy-1,2,3,4-tetrahydrobenzanthracene 
• 148260-34-8 (+)-(3S,4S)-trans-3-bromo-4-menthyloxyacetoxy-1,2,3,4-tetrahydrobenzanthracene 

Downstream Products

• 80433-84-7 (-)-trans-(3S,4S)-3,4-dihydroxy-1,2,3,4-tetrahydrobenzanthracene 

Relevant academic research and scientific papers

Synthesis and Spontaneous Racemization of Benzanthracene 3,4-Oxide: Photochemical Oxygen-walk Rearrangements of Arene Oxides of Benzanthracene and Triphenylene to Yield Oxepines

Benzanthracene 3,4-oxide 2, when synthesised from optically pure dibromo ester precursors, was found to have racemized spontaneously and was accompanied by anthraoxepine 14.Photoisomerization of benzanthracene 3,4-oxide 2, triphenylene 1,2-oxide 4 and benzanthracene 1,2-oxide 5 proceeds via an oxygen-walk mechanism to yield anthraoxepine 14, phenanthrooxepine 16 and anthraoxepine 17 respectively.