89639-84-9Relevant academic research and scientific papers
Oxygen transfer reactions from an oxaziridinium tetrafluoroborate salt to olefins
Lusinchi, Xavier,Hanquet, Gilles
, p. 13727 - 13738 (2007/10/03)
Oxaziridinium 5 efficiently epoxidises olefins. It reacts as an electrophilic reagent and does not transfer its oxygen to deactivated double-bonds or carbonyl functions. Epoxidation of cyclic allylic acetates shows a remarkable diastereoselectivity leading to the syn isomer. We propose that the epoxidation reaction proceeds through a one-step process.
RUTHENIUM-CATALYZED OXIDATION OF 2,3-EPOXYNORBORNANE. INFLUENCE OF THE NATURE OF THE REOXIDIZING REAGENT.
Tenaglia, A.,Terranova, E.,Waegell, B.
, p. 1157 - 1158 (2007/10/02)
The nature of the reoxidizing reagent plays a decisive role in the outcome of the ruthenium-catalyzed oxidation of 2,3-epoxynorbornane.
