896445-03-7

Upstream product

• 607406-41-7 (1S,2R,4R)-2-[(E)-3-(tert-butyldiphenylsiloxy)-1-methyl-1-propenyl]-5-[3-(methoxymethoxy)propyl]-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-ol 
• 607406-39-3 (1S,2R,4R)-5-[3-(methoxymethoxy)propyl]-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-ol 
• 607406-40-6 (1S,4R)-5-[3-(methoxymethoxy)propyl]-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-one 
• 10293-02-4 (1S,2R)-1-methyl-2-hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-5-one 
• 923570-71-2 5-(3-(methoxymethoxy)propyl)-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl pivalate 
• 923570-69-8 5-(3-hydroxypropyl)-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl pivalate 
• 923570-68-7 5-allyl-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl pivalate 
• 923570-67-6 2,2-Dimethyl-propionic acid (1S,2R,4S)-5-hydrazono-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 923570-65-4 1,7,7-trimethyl-5-oxobicyclo[2.2.1]heptan-2-yl pivalate 
• 923570-66-5 5-iodo-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl pivalate 

Downstream Products

• 923570-80-3 (3aR,5S,6S,7S,7aR)-7-((tert-butyldiphenylsilyloxy)methyl)-7a-(3-(methoxymethoxy)propyl)-2,3,3,6-tetramethyl-3a,4,5,6,7,7a-hexahydro-3H-inden-5-ol 
• 923571-04-4 (3R,3aR,6aS,8S,9S,10S,10aR)-5-(tert-butyldimethylsilyloxy)-10-((tert-butyldiphenylsilyloxy)methyl)-3a-hydroxy-3-(methoxymethoxy)-6,6,9-trimethyl-1,2,3,3a,6,6a,7,8,9,10-decahydrocyclopenta[j]naphthalen-8-yl pivalate 
• 923571-06-6 (3R,3aS,4R,5R,6aS,8S,9S,10S,10aR)-10-((tert-butyldiphenylsilyloxy)methyl)-3a,4,5-trihydroxy-3-(methoxymethoxy)-6,6,9-trimethyldodecahydrocyclopenta[j]naphthalen-8-yl pivalate 
• 923571-05-5 (3R,3aS,4S,6aR,8S,9S,10S,10aR)-10-((tert-butyldiphenylsilyloxy)methyl)-3a,4-dihydroxy-3-(methoxymethoxy)-6,6,9-trimethyl-5-oxo-dodecahydrocyclopenta[j]naphthalen-8-yl pivalate 
• 928852-54-4 2,2-Dimethyl-propionic acid (3R,3aS,5aR,7S,8S,9S,9aR)-9-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-4-hydroxymethyl-3-methoxymethoxy-5,5,8-trimethyl-decahydro-cyclopenta[c]inden-7-yl ester 
• 923570-90-5 (3R,3aS,4S,5aR,7S,8S,9S,9aR)-4-acetoxy-9-((tert-butyldiphenylsilyloxy)methyl)-3-(methoxymethoxy)-5,5,8-trimethyl-decahydro-1H-cyclopenta[i]inden-7-yl pivalate 
• 923571-03-3 (3R,3aR,6aR,8S,9S,10S,10aR)-10-((tert-butyldiphenylsilyloxy)methyl)-3a-hydroxy-3-(methoxymethoxy)-6,6,9-trimethyl-5-oxo-dodecahydrocyclopenta[j]naphthalen-8-yl pivalate 
• 923571-08-8 2-[(2R,5R,6R,8S,9S,10S)-10-(tert-Butyl-diphenyl-silanyloxymethyl)-8-(2,2-dimethyl-propionyloxy)-2-methoxymethoxy-9-methyl-1-oxo-spiro[4.5]dec-6-yl]-2-methyl-propionic acid 
• 923571-01-1 2,2-Dimethyl-propionic acid (2R,5R,6S,7S,8S,10S)-6-(tert-butyl-diphenyl-silanyloxymethyl)-10-(1,1-dimethyl-2-oxo-propyl)-2-methoxymethoxy-7-methyl-1-oxo-spiro[4.5]dec-8-yl ester 
• 923570-88-1 (3R,3aR,4S,5aR,7S,8S,9S,9aR)-9-((tert-butyldiphenylsilyloxy)methyl)-4-hydroxy-3-(methoxymethoxy)-5,5,8-trimethyl-decahydro-1H-cyclopenta[i]inden-7-yl pivalate 
• 923571-09-9 2,2-Dimethyl-propionic acid (3R,3aS,6aR,8S,9S,10S,10aS)-10-(tert-butyl-diphenyl-silanyloxymethyl)-3a-hydroxy-3-methoxymethoxy-6,6,9-trimethyl-decahydro-4,5-dioxa-cyclopenta[d]naphthalen-8-yl ester 
• 923570-85-8 (3R,3aR,5aR,7S,8S,9S,9aR)-9-((tert-butyldiphenylsilyloxy)methyl)-3-(methoxymethoxy)-5,5,8-trimethyl-4-methylene-decahydro-1H-cyclopenta[i]inden-7-yl pivalate 
• 923570-91-6 (3R,3aS,4S,5aR,7S,8S,9S,9aR)-4-acetoxy-9-((tert-butyldiphenylsilyloxy)methyl)-3-hydroxy-5,5,8-trimethyl-decahydro-1H-cyclopenta[i]inden-7-yl pivalate 
• 923571-10-2 2,2-Dimethyl-propionic acid (3R,3aS,5aR,7S,8S,9S,9aS)-9-(tert-butyl-diphenyl-silanyloxymethyl)-3a-hydroxy-3-methoxymethoxy-5,5,8-trimethyl-decahydro-benzo[c]cyclopenta[b]furan-7-yl ester 

Relevant academic research and scientific papers

Studies toward the total synthesis of dumsin. 2. A second generation approach resulting in enantioselective construction of a functionalized ABC subunit of the tetranortriterpenoid insect antifeedant

A synthesis of the ABC framework of dumsin is described. The optically active intermediate 9b, which is expeditiously assembled from 5-oxobornyl pivalate by the sequential implementation of an oxy-Cope rearrangement and an intramolecular ene reaction, pro

Alkali metal counterion control of enolate protonation stereoselectivity

Generation of the lithium salt of the norbornenol shown (M = H) followed by quenching with aqueous NH4Cl solution gives predominantly the β-epimeric ketone 6. Similar production of the potassium alkoxide leads instead to the α-epimer (99:1). Th