896451-40-4

Upstream product

• 896451-25-5 (2S,4S,5R,6S)-1-benzyloxy-4-methoxy-2,6-dimethylnon-7-yn-5-ol 
• 896451-31-3 (2S,4S,5R,6S)-1-benzyloxy-4,5-dimethoxy-2,6-dimethyl-7-nonyne 
• 896451-26-6 (E)-(2S,3R,6S,7R,8S,10S)-11-(benzyloxy)-1-(tert-butyldiphenylsilyloxy)-7,8-dimethoxy-2,4,6,10-tetramethylundec-4-en-3-ol 

Relevant academic research and scientific papers

Studies on the syntheses of benzoquinone ansamycin antibiotics. Syntheses of the C(5)-C(15) subunits of macbecin I, geldanamycin, and herbimycin A

A general and convergent route to the C(5)-C(15) subunits of the benzoquinone ansamycin antibiotics macbecin I, geldanamycin, and herbimycin A is described. Each subunit is prepared by the stepwise coupling of differentially functionalized aldehydes with