89652-40-4Relevant academic research and scientific papers
PHOTOCYCLIZATION OF ENAMIDES. XXVIII. A FORMAL TOTAL SYNTHESIS OF (+/-)-DESERPIDINE
Naito, Takeaki,Hirata, Yumiko,Miyata, Okiko,Ninomiya, Ichiya,Inoue, Masatoshi,et al.
, p. 901 - 906 (2007/10/02)
A formal totalsynthesis of (+/-)-deserpidine (1) was accomplished by preparing the known synthetic precursors, two hydroxyesters 19 and 20, via a route involving regioselective formation of the 18-methoxyenone 10a followed by regioselective C-acylation of the enone 10a.Keywords: deserpidine; total synthesis; yohimbine; reserpine; indole alkaloid; photocyclization; enamide; epoxyketone
