896735-84-5Relevant academic research and scientific papers
One-pot optical resolution of oligopeptide helices through artificial peptide bundling
Guo, Yan-Ming,Oike, Hideaki,Saeki, Naoko,Aida, Takuzo
, p. 4915 - 4918 (2007/10/03)
The helical sense of the peptidic parts of a cyclodimeric zinc porphyrin host with helical oligopeptide units (1) determines whether a right- or left-handed oligopeptide guest (2) is selectively bound (see picture). In contrast, enantiomers of nonhelical
Chiroptical Transcription of Helical Information through Supramolecular Harmonization with Dynamic Helices
Guo, Yan-Ming,Oike, Hideaki,Aida, Takuzo
, p. 716 - 717 (2007/10/03)
With biologically important "peptide bundling" as the motif, new chromophoric cyclic host 1 was designed, which consists of two zinc porphyrin units that are connected by dynamic peptide helices of nonameric aminoisobutyric acid (Aib) units. Upon inclusio
