89690-27-7Relevant academic research and scientific papers
Synthesis of chiral building blocks for oxygenated terpenoids through a simultaneous and stereocontrolled construction of contiguous quaternary stereocenters by an ireland-claisen rearrangement
Akahori, Yoshihiro,Yamakoshi, Hiroyuki,Sawayama, Yuki,Hashimoto, Shunichi,Nakamura, Seiichi
, p. 720 - 735 (2014/04/03)
Methods for highly stereocontrolled syntheses of chiral building blocks with a triad of contiguous stereocenters, including two quaternary ones, have been developed. Ireland-Claisen rearrangement of the (Z)-silyl ketene acetal generated stereoselectively
TOTAL SYNTHESIS OF ( plus )-PHYLLANTHOCIN.
Williams,Sit
, p. 2949 - 2954 (2007/12/18)
Investigations culminating in the total synthesis of ( plus )-phyllanthocin via a highly convergent route beginning with natural tartaric acid are reported. The stereochemical consequences of internal spiroketalization with protic acid and Lewis acid chel
